Hybrid high temperature insulation

ABSTRACT

According to one aspect, a hybrid high temperature thermal insulation includes a mix of inorganic granules. The granular mix includes at least 70 weight percent porous inorganic granules in the form of expanded perlite, and at most 30 weight percent second porous inorganic granules other than expanded perlite. The hybrid insulation also includes a binder. In example formulations, the second porous inorganic particles may be made from crushed aerogel, from fumed silica, from precipitated silica, or from other substances. The hybrid insulation may be formed into preferred shapes, for example a board shape or a semi-cylindrical shape configured to fit over a round tube of a predetermined diameter.

This application is a continuation of U.S. patent application Ser. No.14/610,786 filed Jan. 30, 2015 and titled “Hybrid High TemperatureInsulation”, now U.S. Pat. No. 9,593,797, the entire contents of whichare hereby incorporated by reference herein for all purposes.

BACKGROUND OF THE INVENTION

Insulating structures or equipment in high temperature environmentspresents special challenges. For example, some industrial processesinvolve piping or containers holding fluids at temperatures approaching1200° F. or more. Thermal insulation may be provided to reduce the lossof valuable heat from a process, to maintain proper reactiontemperatures, for the safety and comfort of personnel working near theprocess, and other reasons.

Besides preferably having a low thermal conductivity, a basicrequirement of insulation in such applications is that it be able towithstand the high temperatures without degradation. Preferably, thematerial should also be strong enough to withstand handling withoutexcessive damage, light in weight if possible, resistant to chemicalattack, and non-combustible. Due to the requirement to withstand hightemperatures, such insulation is often made of inorganic materials suchas mineral fibers, calcium silicate, and perlite.

BRIEF SUMMARY OF THE INVENTION

According to one aspect, a hybrid high temperature thermal insulationcomprises a mix of inorganic granules. The granular mix comprises atleast 70 weight percent first porous inorganic granules in the form ofexpanded perlite, and at most 30 weight percent second porous inorganicgranules. The second porous inorganic granules are other than expandedperlite. The hybrid high temperature insulation further comprises abinder. The second porous inorganic granules may comprise aerogelparticles. The second porous inorganic granules may comprise silicaaerogel particles. The second porous inorganic granules may comprisefumed silica particles. The second porous inorganic granules maycomprise precipitated silica particles. In some embodiments, the binderis sodium silicate. In some embodiments, the hybrid high temperaturethermal insulation further comprises reinforcing fibers. In someembodiments, the insulation has a density of between 9 and 16 lbs/ft³.In some embodiments, the insulation has a thermal conductivity of lessthan 0.6 BTU-in/(ft²-h-° F.) when measured at 500° F. In someembodiments, the insulation has a thermal conductivity of less than 0.5BTU-in/(ft²-h-° F.) when measured at 500° F. In some embodiments, thesecond porous inorganic granules are hydrophobic. In some embodiments,the second porous inorganic granules comprise an organic coating thatrenders the second porous inorganic granules hydrophobic. The secondporous inorganic granules may be hydrophilic. In some embodiments themix comprises at least 80 weight percent expanded perlite. In someembodiments, the mix comprises at least 85 weight percent expandedperlite. In some embodiments, the mix comprises at least 90 weightpercent expanded perlite. In some embodiments, the mix comprises atleast 94 weight percent expanded perlite.

According to another aspect, a method of making thermal insulationcomprises forming a mixture having at least 70 weight percent porousinorganic granules in the form of expanded perlite and at most 30 weightpercent second porous inorganic granules, the second porous inorganicgranules being other than expanded perlite. The method further comprisesadding a binder to the mixture, pressing the mixture to a predeterminedshape, and oven drying the pressed shape. In some embodiments, pressingthe mixture to a predetermined shape comprises pressing the mixture intoa hollow semi-cylindrical shape configured to fit over a round tube of apredetermined diameter. In some embodiments, pressing the mixture to apredetermined shape comprises pressing the mixture into a board shape.The method may further comprise cutting the predetermined shape to afinal size. In some embodiments, the second porous inorganic granulescomprise aerogel particles. In some embodiments, the second porousinorganic granules comprise fumed silica particles or precipitatedsilica particles.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 illustrates a system and method of making a hybrid insulationproduct, in accordance with embodiments of the invention.

FIGS. 2A and 2B illustrate board and semi-cylindrical shapes, inaccordance with embodiments of the invention.

FIG. 3 illustrates the thermal performance of several example hybridinsulation compositions in accordance with embodiments of the invention,as well as the thermal performance of perlite insulation withoutsecondary granules, and the thermal performance of aerogel granulesalone.

DETAILED DESCRIPTION OF THE INVENTION

High temperature insulation has been made from expanded perlite. Perliteis a naturally occurring volcanic glass that has a significant watercontent. When perlite is rapidly heated to 1560-1650° F., water trappedin the structure vaporizes and escapes, greatly expanding the moltenglass material in the process. Unexpanded perlite “ore” has a typicalbulk density of about 1.1 g/cm³, while expanded perlite has a typicalbulk density between 0.03 and 0.15 g/cm³. Expanded perlite is composedof granules and can be used for many purposes, including insulation.Expanded perlite is generally white, due to the reflectivity of bubblestrapped in the material. Thus, expanded perlite is a porous inorganicmaterial made up of granules of foamed glass with both closed and opencells.

In forming insulation, the expanded perlite granules are typically mixedwith a binder, for example sodium silicate or another suitable binder,to form a mixture that can be pressed into preferred shapes. The mixturemay be pressed into rectangular blocks or boards, into semi-cylindricalshapes figured to fit over piping, or other shapes. The unpressedmixture may have a bulk density of about 4-5 lbs/ft³ and the pressedshape may typically have a density of about 13-15 lbs/ft³, althoughother densities are possible. The resulting article is then dried,typically in an oven, and may be cut to preferred dimensions. Forexample pipe insulation may be cut to specific lengths, and boardinsulation may be cut to a specific length, width, and thickness.

The thermal conductivity of perlite insulation is temperature-dependent,and may typically range, for example, from about 0.47 BTU-in/(hr-ft²-°F.) at 100° F. to about 0.85 BTU-in/(hr-ft²-° F.) at 800° F.

According to embodiments of the invention, a second kind of porousinorganic granules are included in insulation, in addition to expandedperlite granules. At least some performance properties of the resultinginsulation may be improved as compared with insulation made from perlitegranules alone.

In some embodiments, the second inorganic granules are aerogelparticles. An aerogel is a very light weight porous material derivedfrom a gel in which the liquid component of the gel has been replacedwith a gas. While aerogels can be made from a variety of materials,silica aerogel is common. Silica aerogel typically has a density ofabout 150 Kg/m³, and may have a thermal conductivity as low as 0.02W/(m-K). Silica aerogel particles are commercially available, forexample from Cabot Corporation of Boston, Mass., USA. In someembodiments, aerogel particles having a characteristic size of about0.04-0.2 mm may be used, although other sizes may be used in otherembodiments.

In other embodiments, the second inorganic granules are made from fumedsilica. Fumed silica may be made from microscopic droplets of amorphoussilica fused into branched, chainlike, three-dimensional secondaryparticles which then agglomerate into tertiary particles. The resultingpowder has an extremely low bulk density and high surface area. Fumedsilica is typically made in a flame. Bulk fumed silica is porous, andhas a density much lower than the density of the base silica material.For the purposes of this disclosure, “porous” includes materials inwhich small passages exist within the material. In some embodiments,fumed silica particles having a characteristic size of about 5-400 μmmay be used, although other sizes may be used in other embodiments.

In other embodiments, the second porous inorganic granules are made fromprecipitated silica. Precipitated silica is typically made byprecipitation from a solution containing silicate salts. The resultingfine particles are porous, and have a bulk density lower than thedensity of the base silica material. In some embodiments, precipitatedsilica particles having a characteristic size of about 8-12 μm may beused, although other sizes may be used as well.

In some embodiments in which the second granules are made from silica,the granules may be hydrophobic or hydrophilic. For example, hydrophobicfumed silica is typically made by bonding alkyl or polydimethylsiloxanegroups to the silica. Untreated fumed silica may be hydrophilic. For thepurposes of this disclosure, inorganic granules having an organiccoating to render them hydrophobic are still considered to be inorganicgranules.

FIG. 1 illustrates a system and method 100 of making a hybrid insulationproduct, in accordance with embodiments of the invention. As shown inFIG. 1, raw perlite granules 101 are fed to an expander 102. Forexample, raw perlite granules 101 may have a size distribution rangingfrom about 40 to about 800 microns, although other particle sizes may beused in other embodiments. Raw perlite granules are readily commerciallyavailable from a number of suppliers. Expander 102 heats the rawgranules, causing them to expand as described above, due to theexpansion of water trapped in the raw perlite ore. The granules may alsofracture, so that each ore granule may create multiple expandedparticles. The expanded perlite particles may be fed to one or morecyclones 103 or other devices for separating the particles by size. Forexample, particles having a characteristic dimension of 50 to 1000microns may be used in forming the hybrid insulation, while finerparticles 104 may be deemed not suitable for use in the hybridinsulation. The finer particles 104 may be separated and removed, foruse in making other products or for use in other industrial processes.In other embodiments, other size ranges may be used.

The expanded perlite particles deemed usable for making insulation arefed to a mixer 105, along with the secondary granules 106. Mixer 105 maybe, for example, a batch or continuous mixer. Secondary granules 106 maybe, for example, aerogel particles, fumed silica particles, orprecipitated silica particles as described above. A binder 107 ispreferably added, for example sodium silicate. Other additives may beadded to the mixer as well, for example one or more opacifiers,reinforcing fibers, or the like.

Reinforcing fibers may add strength to the hybrid insulation and reduceits brittleness. Reinforcing fibers may be made of, for example, glass,polyester, or other materials or combinations of materials. Thereinforcing fibers may be of any workable dimensions, for example fromabout ¼ inch to 1.5 inches in length, and about 2 to 25 μm in diameter,although other dimensions may be used as well.

The mixture may then be pressed 108 into preliminary shapes, for examplesheets or semi-cylindrical shapes. The shapes may then be dried 109, forexample in a drying oven, and then cut 110 to final dimensions. Thefinished insulation elements may then be packaged 111 for shipping. FIG.2A illustrates insulation formed into a board shape 201, and FIG. 2Bshows insulation formed into a semi-cylindrical shape 202, in accordancewith embodiments of the invention. For example, inner surface 203 ofshape 202 may be sized to fit over a pipe of a particular diameter. Arange of insulation sizes may be produced for us in differentapplications.

EXAMPLES

A number of example hybrid materials have been constructed, according tothe data shown in Table 1 below.

TABLE 1 Makeup of Examples Weight % Secondary secondary Secondary Sample# Particle type particles particle size 0 None 0 — 1 Silica Aerogel 50.06-0.1 mm 2 Silica Aerogel 10 0.06-0.1 mm 3 Hydrophobic 10 10-200 μmfumed silica 4 Hydrophobic 10 9.5 μm precipitated silica 5 Hydrophilic10 10-200 μm fumed silica 6 Silica Aerogel 30 0.01-1.2 mm

Table 2 shows certain physical properties of the samples listed in Table1, as available. Linear shrinkage refers to the shrinkage of thefinished insulation product when subjected to high temperatures, forexample 1200° F., which may be higher than the temperatures used inmanufacturing of the insulation. Water absorption refers to the changein weight of the insulation after soaking in water. Compression strengthrefers to the compressive stress that produces a 5% compression of theproduct. Flexural strength refers to the bending stress required tocause a fracture of the product. Friability refers to the tendency ofthe insulation product to crumble during handling and shipping, and maybe measured, for example, by tumbling one-inch cubes of the material for10 minutes and measuring the weight loss of the cubes in the tumblingprocess.

TABLE 2 Physical Properties Linear Water Compression Flexural Densityshrinkage absorption Strength Strength Friability Sample # (lb/ft³) (%)(%) (lb/in²) (lb/in²) (% Loss) 0 14.9 0.08 12.98 56 37 77.0 1 14.5 2.3711.55 37 31 79.2 2 13.2 4.75 12.35 15 13 99.8 3 14.7 1.14 17.36 42 2784.7 4 15.3 1.00 17.53 49 24 84.0 5 15.1 0.25 13.81 48 22 88.4 6 9.8

Table 3 lists thermal performance data for the samples listed inTable 1. FIG. 3 illustrates the thermal performance of the examplecompositions, as well as the thermal performance of perlite insulationwithout secondary particles (example #0), and the thermal performance ofaerogel particles alone.

TABLE 3 Thermal Conductivity (BTU-in/(ft²-h-° F.)) at listedtemperatures. Sample # 100° F. 300° F. 500° F. 700° F. 900° F. 0 0.4740.551 0.635 0.727 0.826 1 0.422 0.486 0.567 0.663 0.776 2 0.364 0.4160.495 0.601 0.733 3 0.447 0.515 0.592 0.678 0.774 4 0.452 0.525 0.6070.697 0.795 5 0.457 0.533 0.617 0.709 0.809 6 0.234 0.287 0.386 0.5310.722

As is apparent from the above tables and from FIG. 3, hybrid insulationproducts according to embodiments of the invention may have superiorinsulating properties as compared with insulation made from perlitewithout any secondary granules, and at some temperatures may have alower thermal conductivity than even aerogel particles alone. For anyparticular application, the preferred combination of perlite andsecondary granules will depend on a large number of factors, for examplethe relative costs of perlite and the secondary granules, physicalstrength requirements, shipping and handling costs, and other factors.

Because a hybrid insulation embodying the invention may have a lowerthermal conductivity than perlite insulation made without secondarygranules, it may be possible to use a thinner hybrid insulation in placeof perlite insulation, to achieve the same insulating performance. Thethinner insulation takes up less space in situ and during shipping, andmay result in lower shipping and storage costs. Alternatively, hybridinsulation at least as thick as alternative perlite insulation may beused, resulting in reduced heat loss as compared with perliteinsulation.

Having described several embodiments, it will be recognized by those ofskill in the art that various modifications, alternative constructions,and equivalents may be used without departing from the spirit of theinvention. Additionally, a number of well-known processes and elementshave not been described in order to avoid unnecessarily obscuring thepresent invention. Accordingly, the above description should not betaken as limiting the scope of the invention.

Where a range of values is provided, it is understood that eachintervening value, to the tenth of the unit of the lower limit unlessthe context clearly dictates otherwise, between the upper and lowerlimits of that range is also specifically disclosed. Each smaller rangebetween any stated value or intervening value in a stated range and anyother stated or intervening value in that stated range is encompassed.The upper and lower limits of these smaller ranges may independently beincluded or excluded in the range, and each range where either, neitheror both limits are included in the smaller ranges is also encompassedwithin the invention, subject to any specifically excluded limit in thestated range. Where the stated range includes one or both of the limits,ranges excluding either or both of those included limits are alsoincluded.

As used herein and in the appended claims, the singular forms “a”, “an”,and “the” include plural referents unless the context clearly dictatesotherwise. Thus, for example, reference to “a process” includes aplurality of such processes and reference to “the device” includesreference to one or more devices and equivalents thereof known to thoseskilled in the art, and so forth.

Also, the words “comprise,” “comprising,” “include,” “including,” and“includes” when used in this specification and in the following claimsare intended to specify the presence of stated features, integers,components, or steps, but they do not preclude the presence or additionof one or more other features, integers, components, steps, acts, orgroups.

What is claimed is:
 1. A hybrid high temperature thermal insulation,comprising: a mix of inorganic granules, the mix comprising at least 70weight percent first porous inorganic granules in the form of expandedperlite, and at most 30 weight percent second porous inorganic granules,the second porous inorganic granules being other than expanded perlite;and a binder; wherein the insulation has a thermal conductivity of lessthan 0.6 BTU-in/(ft²-h-° F.) when measured at 500° F.; and wherein thesecond porous inorganic granules comprise aerogel particles.
 2. Thehybrid high temperature thermal insulation of claim 1, wherein thesecond porous inorganic granules comprise silica aerogel particles. 3.The hybrid high temperature thermal insulation of claim 1, wherein thebinder is sodium silicate.
 4. The hybrid high temperature thermalinsulation of claim 1, further comprising reinforcing fibers.
 5. Thehybrid high temperature thermal insulation of claim 1, wherein theinsulation has a thermal conductivity of less than 0.5 BTU-in/(ft²-h-°F.) when measured at 500° F.
 6. The hybrid high temperature thermalinsulation of claim 1, wherein the second porous inorganic granules arehydrophobic.
 7. The hybrid high temperature thermal insulation of claim6, wherein the second porous inorganic granules comprise an organiccoating that renders the second porous inorganic granules hydrophobic.8. The hybrid high temperature thermal insulation of claim 1, whereinthe second porous inorganic granules are hydrophilic.
 9. The hybrid hightemperature thermal insulation of claim 1, wherein the mix comprises atleast 80 weight percent expanded perlite.
 10. The hybrid hightemperature thermal insulation of claim 1, wherein the mix comprises atleast 85 weight percent expanded perlite.
 11. The hybrid hightemperature thermal insulation of claim 1, wherein the mix comprises atleast 90 weight percent expanded perlite.
 12. The hybrid hightemperature thermal insulation of claim 1, wherein the mix comprises atleast 94 weight percent expanded perlite.
 13. A hybrid high temperaturethermal insulation, comprising: a mix of inorganic granules, the mixcomprising at least 70 weight percent first porous inorganic granules inthe form of expanded perlite, and at most 30 weight percent secondporous inorganic granules, the second porous inorganic granules beingother than expanded perlite; and a binder; wherein the second porousinorganic granules comprise precipitated silica particles.
 14. Thehybrid high temperature thermal insulation of claim 13, wherein theinsulation has a thermal conductivity of about 0.607 BTU-in/(ft²-h-° F.)when measured at 500° F.
 15. The hybrid high temperature thermalinsulation of claim 14, wherein the second porous inorganic granulescomprise an organic coating that renders the second porous inorganicgranules hydrophobic.
 16. A hybrid high temperature thermal insulation,comprising: a mix of inorganic granules, the mix comprising at least 70weight percent first porous inorganic granules in the form of expandedperlite, and at most 30 weight percent second porous inorganic granules,the second porous inorganic granules being other than expanded perlite;and a binder; wherein the second porous inorganic granules comprisesilica aerogel particles.
 17. The hybrid high temperature thermalinsulation of claim 16, further comprising reinforcing fibers.
 18. Thehybrid high temperature thermal insulation of claim 16, wherein the mixcomprises at least 80 weight percent expanded perlite.
 19. The hybridhigh temperature thermal insulation of claim 16, wherein the mixcomprises at least 90 weight percent expanded perlite.